您还可以使用XPath读取元素的值:

Dim doc As XmlDocument = New XmlDocument()
doc.Load("C:\members.xml")
Dim kills As String = doc.SelectNode("Tabel/Member[Naam='Ghostbullet93']/Kills").InnerText

但是，如果您打算加载和使用所有数据，则使用序列化会容易得多.为此，您首先需要创建模仿XML结构的类(为简单起见，我将仅使用公共字符串字段，但***使用属性):

Public Class Member
    Public Naam As String
    Public Kills As Integer
    Public Deaths As Integer
    Public KD As Integer
End Class

Public Class Tabel
    <XmlElement("Member")> _
    Public Members As List(Of Member)
End Class

然后像这样反序列化XML:

Dim serializer As XmlSerializer = New XmlSerializer(GetType(Tabel))
Dim tabel As Tabel = CType(serializer.Deserialize(File.OpenRead("C:\members.xml")), Tabel)
For Each member As Member in tabel
    Dim kills As Integer = member.Kills
Next

From this XML code:

<?xml version="1.0" encoding="utf-8"?>
<Tabel>
  <Member>
    <Naam>Cruciatum</Naam>
    <Kills>1000</Kills>
    <Deaths>10</Deaths>
    <KD>100</KD>
  </Member>
  <Member>
    <Naam>Ghostbullet93</Naam>
    <Kills>10</Kills>
    <Deaths>1</Deaths>
    <KD>10</KD>
  </Member>
</Tabel>

How can I get (for example) the 10 next to <Kills> ?

I've tried multiple things without any success. One of the ideas I had was using this code:

Dim doc = XDocument.Load("C:\members.xml")
        Dim members = From m In doc.Element("Tabel").Elements("Member")
                      Select naam = m.Element("Naam").Value
        For Each member In members
            lstmembers.Items.Add(member)
        Next

But I can't figure out how to edit that snippet to work with what I need it to do now.

(The above code works perfectly for where it's used.)

You can also use XPath to read the element's value:

Dim doc As XmlDocument = New XmlDocument()
doc.Load("C:\members.xml")
Dim kills As String = doc.SelectNode("Tabel/Member[Naam='Ghostbullet93']/Kills").InnerText

If, however, you intend to load and use all the data, it would be far easier to use serialization. To do that, you first need to create classes that mimic the XML structure (for simplicity sake I'll just use public string fields, but it would be better to use properties):

Public Class Member
    Public Naam As String
    Public Kills As Integer
    Public Deaths As Integer
    Public KD As Integer
End Class

Public Class Tabel
    <XmlElement("Member")> _
    Public Members As List(Of Member)
End Class

Then deserialize the XML like this:

Dim serializer As XmlSerializer = New XmlSerializer(GetType(Tabel))
Dim tabel As Tabel = CType(serializer.Deserialize(File.OpenRead("C:\members.xml")), Tabel)
For Each member As Member in tabel
    Dim kills As Integer = member.Kills
Next