试试这个 (msdn):

<ComboBox x:Name="ComboBoxOperatingPoints"  
          SelectionChanged="ComboBoxOperatingPoints_SelectionChanged" 
          Width="200" Height="50"
          IsSynchronizedWithCurrentItem="True"
          DisplayMemberPath="name"        
          SelectedValuePath="operating_point_id">
    <ComboBox.Resources>
        <CollectionViewSource x:Key="comboBoxSource" Source="{Binding Path=OperatingPoints}" />
    </ComboBox.Resources>
    <ComboBox.ItemsSource>
        <CompositeCollection>
            <local:OpPoint name="all" operating_point_id="-1" />
            <CollectionContainer Collection="{Binding Source={StaticResource comboBoxSource}}" />
        </CompositeCollection>
    </ComboBox.ItemsSource>
</ComboBox>