我认为您可以使用

I think you can use values, it convert column Value to array:

ts = pd.Series(df['Value'].values, index=df['Date'])

import pandas as pd
import numpy as np
import io

dates = ['2016-1-{}'.format(i)for i in range(1,21)]
values = [i for i in range(20)]
data = {'Date': dates, 'Value': values}
df = pd.DataFrame(data)
df['Date'] = pd.to_datetime(df['Date'])
print df['Value'].values
[ 0  1  2  3  4  5  6  7  8  9 10 11 12 13 14 15 16 17 18 19]

ts = pd.Series(df['Value'].values, index=df['Date'])

print(ts)
Date
2016-01-01     0
2016-01-02     1
2016-01-03     2
2016-01-04     3
2016-01-05     4
2016-01-06     5
2016-01-07     6
2016-01-08     7
2016-01-09     8
2016-01-10     9
2016-01-11    10
2016-01-12    11
2016-01-13    12
2016-01-14    13
2016-01-15    14
2016-01-16    15
2016-01-17    16
2016-01-18    17
2016-01-19    18
2016-01-20    19
dtype: int64

或者您可以使用:

ts1 = pd.Series(data=values, index=pd.to_datetime(dates))
print(ts1)
2016-01-01     0
2016-01-02     1
2016-01-03     2
2016-01-04     3
2016-01-05     4
2016-01-06     5
2016-01-07     6
2016-01-08     7
2016-01-09     8
2016-01-10     9
2016-01-11    10
2016-01-12    11
2016-01-13    12
2016-01-14    13
2016-01-15    14
2016-01-16    15
2016-01-17    16
2016-01-18    17
2016-01-19    18
2016-01-20    19
dtype: int64

谢谢您 @ajcr 以获得更好的解释，为什么会出现NaN:

Thank you @ajcr for better explanation why you get NaN:

将Series或DataFrame列提供给pd.Series时，它将使用您指定的index重新编制索引.由于您的DataFrame列具有整数index(而不是date index)，因此会出现很多缺失值.

When you give a Series or DataFrame column to pd.Series, it will reindex it using the index you specify. Since your DataFrame column has an integer index (not a date index) you get lots of missing values.