SELECT  DATE_FORMAT(PunchDateTime, '%W') DAY,
        MAX(CASE WHEN PunchEvent = 'ClockIn' THEN DATE_FORMAT(PunchDateTime, '%r') END) ClockIn,
        MAX(CASE WHEN PunchEvent = 'BreakOut' THEN DATE_FORMAT(PunchDateTime, '%r') END) BreakOut,
        MAX(CASE WHEN PunchEvent = 'BreakIn' THEN DATE_FORMAT(PunchDateTime, '%r') END) BreakIn,
        MAX(CASE WHEN PunchEvent = 'ClockOut' THEN DATE_FORMAT(PunchDateTime, '%r') END) ClockOut
FROM    tableName
WHERE   EmpID = 456
GROUP   BY DATE_FORMAT(PunchDateTime, '%W')
ORDER   BY PunchDateTime

• SQLFiddle演示
• SQLFiddle Demo

输出

╔═══════════╦═════════════╦═════════════╦═════════════╦═════════════╗
║    DAY    ║   CLOCKIN   ║  BREAKOUT   ║   BREAKIN   ║  CLOCKOUT   ║
╠═══════════╬═════════════╬═════════════╬═════════════╬═════════════╣
║ Tuesday   ║ 08:36:26 AM ║ 12:01:29 PM ║ 12:28:31 PM ║ 02:28:33 PM ║
║ Wednesday ║ 07:38:34 AM ║ 07:38:39 AM ║ 07:38:41 AM ║ 07:38:42 AM ║
╚═══════════╩═════════════╩═════════════╩═════════════╩═════════════╝