这应该是像下面这样。我写这个的答案框，以便语法可能不完全正确的，但我做了它的wiki编辑的所以任何人都可以解决了。

It should be something like the following. I wrote this in the answer box so the syntax may not be exactly right, but I've made it Wiki editable so anybody can fix up.

if (listBox.ItemsSource.IsGenericType && 
    typeof(IDictionary<,>).IsAssignableFrom(listBox.ItemsSource.GetGenericTypeDefinition()))
{
    var method = typeof(KeyValuePair<,>).GetProperty("Value").GetGetMethod();
    var item = method.Invoke(listBox.SelectedItem, null);
}