您POCO实体是完全可序列化。你的问题是，动态代理的EF运行时会为你通常不会。您可以设置context.Configuration.ProxyCreationEnabled为false，但你失去延迟加载。我强烈推荐你是使用Json.NET支持序列化EF实体：

http://james.newtonking.com/archive/2009/07/10/ado-net-entity-framework-support-accidently-added-to-json-net.aspx

http://james.newtonking.com/projects/json-net.aspx

Just as mentioned in this post, I am getting a Json serialization error while serializing an Entity Framework Proxy:

A circular reference was detected while serializing an object of type 'System.Data.Entity.DynamicProxies.PurchaseOrder_446B939192F161CDBC740067F174F7A6059B0F9C0EEE68CD3EBBD63CF9AF5BD0'.

But the difference is, I don't have a circular reference in my entities, and it only occurs in our production environment. Locally everything works fine...

My Entities:

public interface IEntity
{
    Guid UniqueId { get; }
    int Id { get; }
} 

public class Entity : IEntity
{
    public int Id { get; set; }
    public Guid UniqueId { get; set; }
}

public class PurchaseOrder : Entity
{
    public string Username { get; set; }
    public string Company { get; set; }

    public string SupplierId { get; set; }
    public string SupplierName { get; set; }

    public virtual ICollection<PurchaseOrderLine> Lines { get; set; }
}

public class PurchaseOrderLine : Entity
{
    public string Code { get; set; }
    public string Name { get; set; }
    public decimal Quantity { get; set; }
}

The GetCurrent action on my PurchaseOrderController throwing the exception:

public class PurchaseOrderController : Controller
{
    private readonly IUnitOfWork _unitOfWork;

    public PurchaseOrderController(IUnitOfWork unitOfWork)
    {
        _unitOfWork = unitOfWork;
    }

    public JsonResult GetCurrent()
    {
        return Json(EnsurePurchaseOrder(), JsonRequestBehavior.AllowGet);
    }

    private PurchaseOrder EnsurePurchaseOrder()
    {
        var company = RouteData.GetRequiredString("company");
        var repository = _unitOfWork.GetRepository<PurchaseOrder>();

        var purchaseOrder = repository
                .Include(p => p.Lines)
                .FirstOrDefault
                (
                    p => p.Company == company && 
                         p.Username == User.Identity.Name
                );

        if (purchaseOrder == null)
        {
            purchaseOrder = repository.Create();
            purchaseOrder.UniqueId = Guid.NewGuid();
            purchaseOrder.Company = company;
            purchaseOrder.Username = User.Identity.Name;
            _unitOfWork.SaveChanges();
        }

        return purchaseOrder;
    }
}

Your POCO entities are perfectly serializable. Your problem is that the dynamic proxies the EF runtime creates for you are usually not. You can set the context.Configuration.ProxyCreationEnabled to false but then you lose lazy loading. My strong recommendation to you is to use Json.NET which supports serialization for EF entities:

http://james.newtonking.com/archive/2009/07/10/ado-net-entity-framework-support-accidently-added-to-json-net.aspx

http://james.newtonking.com/projects/json-net.aspx