您正在运行到一个字节对齐的问题。在试图保持对字边界字段的访问速度，编译器填充您的字符串 3额外的字节。为了解决这个问题，可以使用 StructLayoutAttribute 。

You're running into a byte-alignment issue. In an attempt to keep fields on word boundaries for speed of access, the compiler is padding your string with 3 extra bytes. To fix this, use the Pack field of the StructLayoutAttribute.

[StructLayout(LayoutKind.Sequential, Pack=1)]  // notice the packing here
public struct SFHeader
{
    [MarshalAs(UnmanagedType.ByValTStr, SizeConst = 5)]
    public string FileName;

    public int Offset;

    public short Size;

    public byte Flags;

    public byte Source;

    public long LastWriteTime;
}