你想使用 pack 和 base_convert.

// Convert a string into binary
// Should output: 0101001101110100011000010110001101101011
$value = unpack('H*', "Stack");
echo base_convert($value[1], 16, 2);

// Convert binary into a string
// Should output: Stack
echo pack('H*', base_convert('0101001101110100011000010110001101101011', 2, 16));